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Reactivities of Fe(IV) Complexes with Oxo, Hydroxo, and Alkylperoxo Ligands: An Experimental and Computational Study
In a previous paper (Jensen et al., J. Am. Chem. Soc. 2005, 127, 10512), we reported the synthesis of the turquoise-colored intermediate [Fe(IV)(β-BPMCN)(OO(t)Bu)(OH)](2+) (Tq; BPMCN = N,N′-bis(2-pyridylmethyl)-N,N′-dimethyl-trans-1,2-diaminocyclohexane). The structure of Tq is unprecedented, as it...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2789986/ https://ncbi.nlm.nih.gov/pubmed/19863068 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic901391y |
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