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Determination of the Substrate Binding Mode to the Active Site Iron of (S)-2-Hydroxypropylphosphonic Acid Epoxidase Using (17)O-Enriched Substrates and Substrate Analogues
(S)-2-hydroxypropylphosphonic acid epoxidase (HppE) is an O(2)-dependent, nonheme Fe(II)-containing oxidase that converts (S)-2-hydroxypropylphosphonic acid ((S)-HPP) to the regio-and enantiomerically specific epoxide, fosfomycin. Use of (R)-2-hydroxypropylphosphonic acid ((R)-HPP) yields the 2-keto...
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| Asıl Yazarlar: | , , , , , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2007
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2780580/ https://ncbi.nlm.nih.gov/pubmed/17927218 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi701370e |
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