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Selective Labeling of Living Cells by a Photo-Triggered Click Reaction

Photo-triggering of the metal-free azide to acetylene cycloaddition reaction was achieved by masking the triple bond of dibenzocyclooctynes as cyclopropenone. Such masked cyclooctynes do not react with azides in the dark. Irradiation of cyclopropenones results in the efficient (Φ(355) = 0.33) and cl...

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Hlavní autoři: Poloukhtine, Andrei A., Mbua, Ngalle Eric, Wolfert, Margreet A., Boons, Geert-Jan, Popik, Vladimir V.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2776736/
https://ncbi.nlm.nih.gov/pubmed/19860481
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja9054096
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