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Hydroperoxylation by Hydroxyethylphosphonate Dioxygenase

[Image: see text] Hydroxyethylphosphonate dioxygenase (HEPD) catalyzes the O(2)-dependent cleavage of the carbon−carbon bond of 2-hydroxyethylphosphonate (2-HEP) to afford hydroxymethylphosphonate (HMP) and formate without input of electrons or use of any organic cofactors. Two mechanisms have been...

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Autori principali: Whitteck, John T., Cicchillo, Robert M., Donk, Wilfred A. van der
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2009
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2773148/
https://ncbi.nlm.nih.gov/pubmed/19839620
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja906238r
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