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Stereogenic-at-Metal Zn- and Al-based N-Heterocyclic Carbene (NHC) Complexes as Bifunctional Catalysts in Cu-Free Enantioselective Allylic Alkylations
Investigations detailed herein demonstrate the ability of chiral bidentate N-heterocyclic carbenes to promote directly – without the need for a Cu salt – site- and enantioselective C–C bond forming reactions. Within this context, catalytic allylic alkylations of various allylic phosphates with dialk...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2761703/ https://ncbi.nlm.nih.gov/pubmed/19630406 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904654j |
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