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The Enantiomeric Scaffold Approach to Highly Functionalized 1-Oxadecalines: Enantio- and Regiocontrolled [4+2] Cycloadditions of 5-Alkenyl-η(3)-Pyranylmolybenum Complexes
TpMo(CO)(2)(5-alkenyl-η-2,3,4-pyranyl) diene complexes function as excellent chiral scaffolds for the efficient regio- and enantiocontrolled synthesis of highly functionalized 1-oxadecaline derivatives through a novel transition metal-mediated Diels-Alder reaction. Very good to excellent yields and...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2758531/ https://ncbi.nlm.nih.gov/pubmed/17284010 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja067104f |
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