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A bonding model for gold(I) carbene complexes

The last decade has witnessed dramatic growth in the number of reactions catalyzed by electrophilic gold complexes. While proposed mechanisms often invoke the intermediacy of gold-stabilized cationic species, the nature of bonding in these intermediates remains unclear. Herein, we propose that the c...

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Bibliografiske detaljer
Main Authors: Benitez, Diego, Shapiro, Nathan D., Tkatchouk, Ekaterina, Wang, Yiming, Goddard, William A., Toste, F. Dean
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2748951/
https://ncbi.nlm.nih.gov/pubmed/20161015
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.331
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