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A bonding model for gold(I) carbene complexes

The last decade has witnessed dramatic growth in the number of reactions catalyzed by electrophilic gold complexes. While proposed mechanisms often invoke the intermediacy of gold-stabilized cationic species, the nature of bonding in these intermediates remains unclear. Herein, we propose that the c...

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Autors principals: Benitez, Diego, Shapiro, Nathan D., Tkatchouk, Ekaterina, Wang, Yiming, Goddard, William A., Toste, F. Dean
Format: Artigo
Idioma:Inglês
Publicat: 2009
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2748951/
https://ncbi.nlm.nih.gov/pubmed/20161015
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.331
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