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Conformations of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis

The structure of ruthenium-based olefin metathesis catalyst 3 and model π-complex 5 in solution and in the solid state are reported. The N-tolyl ligands, due to their lower symmetry than the traditional N-mesityl substituents, complicate this analysis, but ultimately provide explanation for the enha...

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Bibliografische gegevens
Hoofdauteurs: Stewart, Ian C., Benitez, Diego, O'Leary, Daniel J., Tkatchouk, Ekaterina, Day, Michael W., Goddard, William A., Grubbs, Robert H.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2009
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2638209/
https://ncbi.nlm.nih.gov/pubmed/19146414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8078913
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