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Protonolysis of a Ruthenium-Carbene Bond and Applications in Olefin Metathesis
The synthesis of a ruthenium complex containing an N-heterocylic carbene (NHC) and a mesoionic carbene (MIC) is described wherein addition of a Brønsted acid results in protonolysis of the Ru-MIC bond to generate an extremely active metathesis catalyst. Mechanistic studies implicate a rate-determini...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3121189/ https://ncbi.nlm.nih.gov/pubmed/21574621 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja203070r |
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