Manganese(III)-Mediated Transformations of Phloroglucinols: A Formal Oxidative [4+2] Cycloaddition Leading to Bicyclo[2.2.2]octadiones

[Image: see text] Manganese(III)-mediated oxidative transformations of dearomatized phloroglucinol (1,3,5-trihydroxybenzene) derivatives are reported. A number of cyclization modes have been observed, including polycyclization to afford bicyclo[2.2.2]octadiones via a formal oxidative radical [4+2] c...

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Bibliographic Details
Main Authors: Mitasev, Branko, Porco, John A.
Format: Artigo
Language:Inglês
Published: 2009
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2740479/
https://ncbi.nlm.nih.gov/pubmed/19415907
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol900590t
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