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Manganese(III)-Mediated Transformations of Phloroglucinols: A Formal Oxidative [4+2] Cycloaddition Leading to Bicyclo[2.2.2]octadiones
[Image: see text] Manganese(III)-mediated oxidative transformations of dearomatized phloroglucinol (1,3,5-trihydroxybenzene) derivatives are reported. A number of cyclization modes have been observed, including polycyclization to afford bicyclo[2.2.2]octadiones via a formal oxidative radical [4+2] c...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2740479/ https://ncbi.nlm.nih.gov/pubmed/19415907 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol900590t |
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