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Further Investigation of the Intermolecular Diels-Alder Cycloaddition for the Synthesis of Bicyclo[2.2.2]diazaoctane Alkaloids
The convergent synthesis of bicyclo[2.2.2]diazaoctane structures using an intermolecular Diels−Alder cyclo-addition between a pyrazinone and commercially available fumarate or maleate precursors is reported. High reactivity and stereoselection is observed with both dienophile substrates. Structure v...
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Publicado en: | J Org Chem |
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Main Authors: | , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado: |
2017
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Assuntos: | |
Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6613383/ https://ncbi.nlm.nih.gov/pubmed/29172511 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b02403 |
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