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Further Investigation of the Intermolecular Diels-Alder Cycloaddition for the Synthesis of Bicyclo[2.2.2]diazaoctane Alkaloids

The convergent synthesis of bicyclo[2.2.2]diazaoctane structures using an intermolecular Diels−Alder cyclo-addition between a pyrazinone and commercially available fumarate or maleate precursors is reported. High reactivity and stereoselection is observed with both dienophile substrates. Structure v...

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Détails bibliographiques
Publié dans:J Org Chem
Auteurs principaux: Perkins, Jonathan C., Wang, Xiye, Pike, Robert D., Scheerer, Jonathan R.
Format: Artigo
Langue:Inglês
Publié: 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6613383/
https://ncbi.nlm.nih.gov/pubmed/29172511
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b02403
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