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Three-Coordinate and Four-Coordinate Cobalt Hydride Complexes That React with Dinitrogen
We report the formation and N(2) reactivity of novel cobalt hydride complexes supported by bulky β-diketiminate ligands (L). Addition of KHBEt(3) to LCoCl gives [LCo(μ-H)](2) (1) or K(2)[LCoH](2) (2), depending on the amount of borohydride used. Compound 2 is the first example of a crystallographica...
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| Autores principales: | , , |
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| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2009
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2737074/ https://ncbi.nlm.nih.gov/pubmed/19621923 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja902812y |
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