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New Nitrosyl Derivatives of Diiron Dithiolates Related to the Active Site of the [FeFe]-Hydrogenases

Nitrosyl derivatives of diiron dithiolato carbonyls have been prepared starting from the versatile precursor Fe(2)(S(2)C(n)H(2)(n))(dppv)(CO)(4) (dppv = cis-1,2-bis(diphenylphosphinoethylene). These studies expand the range of substituted diiron(I) dithiolato carbonyl complexes. From [Fe(2)(S(2)C(2)...

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Bibliographic Details
Main Authors: Olsen, Matthew T., Justice, Aaron K., Gloaguen, Frédéric, Rauchfuss, Thomas B., Wilson, Scott R.
Format: Artigo
Language:Inglês
Published: 2008
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2736309/
https://ncbi.nlm.nih.gov/pubmed/19007207
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic801542w
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