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Slow Hydrogen Transfer Reactions of Oxo— and Hydroxo— Vanadium Compounds: the Importance of Intrinsic Barriers
Reactions are described that interconvert vanadium(IV) oxo-hydroxo complexes [V(IV)O(OH)(R(2)bpy)(2)]BF(4) (1a-c) and vanadium(V) dioxo complexes [V(V)O(2)(R(2)bpy)(2)]BF(4) (2a-c) [R(2)bpy = 4,4′-di-t-butyl-2,2′-bipyridine ((t)Bu(2)bpy), a; 4,4′-dimethyl-2,2′-bipyridine (Me(2)bpy), b; 2,2′-bipyridi...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2735118/ https://ncbi.nlm.nih.gov/pubmed/19292442 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja808698x |
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