Nitroxyl Radical plus Hydroxylamine Pseudo Self-Exchange Reactions: Tunneling in Hydrogen Atom Transfer

Bimolecular rate constants have been measured for reactions that involve hydrogen atom transfer (HAT) from hydroxylamines to nitroxyl radicals, using the stable radicals TEMPO(•) (2,2,6,6-tetramethylpiperidine-1-oxyl radical), 4-oxo-TEMPO(•) (2,2,6,6-tetramethyl-4-oxo-piperidine-1-oxyl radical), di-...

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Bibliographic Details
Main Authors: Wu, Adam, Mader, Elizabeth A., Datta, Ayan, Hrovat, David A., Borden, Weston Thatcher, Mayer, James M.
Format: Artigo
Language:Inglês
Published: 2009
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2775461/
https://ncbi.nlm.nih.gov/pubmed/19618933
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904400d
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