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Nitroxyl Radical plus Hydroxylamine Pseudo Self-Exchange Reactions: Tunneling in Hydrogen Atom Transfer
Bimolecular rate constants have been measured for reactions that involve hydrogen atom transfer (HAT) from hydroxylamines to nitroxyl radicals, using the stable radicals TEMPO(•) (2,2,6,6-tetramethylpiperidine-1-oxyl radical), 4-oxo-TEMPO(•) (2,2,6,6-tetramethyl-4-oxo-piperidine-1-oxyl radical), di-...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2009
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2775461/ https://ncbi.nlm.nih.gov/pubmed/19618933 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904400d |
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