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Concise Synthesis of the Bryostatin A-Ring via Consecutive C-C Bond Forming Transfer Hydrogenations
[Image: see text] Under the conditions of C-C bond forming transfer hydrogenation, 1,3-propanediol 1 engages in double asymmetric carbonyl allylation to furnish the C(2)-symmetric diol 2. Double ozonolysis of 2 followed by TBS protection delivers aldehyde 3, which is subject to catalyst directed car...
שמור ב:
| Main Authors: | , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2009
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| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2727624/ https://ncbi.nlm.nih.gov/pubmed/19586066 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901096d |
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