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Chemoselective Tryptophan Labeling with Rhodium Carbenoids at Mild pH
Significant improvements have been made to a previously reported tryptophan modification method using rhodium carbenoids in aqueous solution, allowing the reaction to proceed at pH 6–7. This technique is based on the discovery that tert-butylhydroxyl amine promotes indole modification with rhodium c...
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| 主要な著者: | , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2009
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2722835/ https://ncbi.nlm.nih.gov/pubmed/19366262 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900094h |
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