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Efficient route to 4H-1,3-oxazines through ring expansion of isoxazoles by rhodium carbenoids
Studies related to the total synthesis of elisabethin C led to the discovery of a rhodium-catalyzed cascade sequence involving isoxazole ring expansion and a [4 + 3] cycloaddition. The scope of the isoxazole ring expansion was explored, resulting in the synthesis of a range of 4H-1,3-oxazines in 47–...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587331/ https://ncbi.nlm.nih.gov/pubmed/19148263 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.03.010 |
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