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Efficient route to 4H-1,3-oxazines through ring expansion of isoxazoles by rhodium carbenoids

Studies related to the total synthesis of elisabethin C led to the discovery of a rhodium-catalyzed cascade sequence involving isoxazole ring expansion and a [4 + 3] cycloaddition. The scope of the isoxazole ring expansion was explored, resulting in the synthesis of a range of 4H-1,3-oxazines in 47–...

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Bibliografiska uppgifter
Huvudupphovsmän: Manning, James R., Davies, Huw M. L.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2008
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2587331/
https://ncbi.nlm.nih.gov/pubmed/19148263
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.03.010
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