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Dinuclear nickel complexes modeling the structure and function of the acetyl CoA synthase active site

A dinuclear nickel complex with methyl and thiolate ligands, Ni(dadt(Et))Ni(Me)(SDmp) (2), has been synthesized as a dinuclear Ni(d)–Ni(p)-site model of acetyl-CoA synthase (ACS) (dadt(Et) is N,N′-diethyl-3,7-diazanonane-1,9-dithiolate; Dmp is 2,6-dimesitylphenyl). Complex 2 was prepared via 2 metho...

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Detalhes bibliográficos
Main Authors: Ito, Mikinao, Kotera, Mai, Matsumoto, Tsuyoshi, Tatsumi, Kazuyuki
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2715534/
https://ncbi.nlm.nih.gov/pubmed/19584250
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0900433106
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