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Dinuclear nickel complexes modeling the structure and function of the acetyl CoA synthase active site
A dinuclear nickel complex with methyl and thiolate ligands, Ni(dadt(Et))Ni(Me)(SDmp) (2), has been synthesized as a dinuclear Ni(d)–Ni(p)-site model of acetyl-CoA synthase (ACS) (dadt(Et) is N,N′-diethyl-3,7-diazanonane-1,9-dithiolate; Dmp is 2,6-dimesitylphenyl). Complex 2 was prepared via 2 metho...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2715534/ https://ncbi.nlm.nih.gov/pubmed/19584250 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0900433106 |
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