Thiolate-bridged dinuclear iron(tris-carbonyl)–nickel complexes relevant to the active site of [NiFe] hydrogenase

The reaction of NiBr(2)(EtOH)(4) with a 1:2–3 mixture of FeBr(2)(CO)(4) and Na(SPh) generated a linear trinuclear Fe–Ni–Fe cluster (CO)(3)Fe(μ-SPh)(3)Ni(μ-SPh)(3)Fe(CO)(3), 1, whereas the analogous reaction system FeBr(2)(CO)(4)/Na(S(t)Bu)/NiBr(2)(EtOH)(4) (1:2–3:1) gave rise to a linear tetranuclea...

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Bibliografiske detaljer
Main Authors: Ohki, Yasuhiro, Yasumura, Kazunari, Kuge, Katsuaki, Tanino, Soichiro, Ando, Masaru, Li, Zilong, Tatsumi, Kazuyuki
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2008
Fag:
Physical Sciences
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2409409/
https://ncbi.nlm.nih.gov/pubmed/18511566
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0800538105
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