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Computational Studies on the Pt(II)-Catalyzed Cycloisomerization of 1,6-dienes into Bicyclopropanes: A Mechanistic Quandary Evaluated by DFT

The mechanism of the (bis(phosphanylethyl)phosphane)Pt(2+) catalyzed cyclo-isomerization reaction of 7-methyl-octa-1,6-diene to form 1-isopropylbicyclo[3.1.0]hexane was studied using computational methods. The cyclopropanation step was found to be the turnover-limiting step. The overall reaction pro...

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Autori principali: Bell, Franziska, Holland, Jason, Green, Jennifer C., Gagné, Michel R.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2009
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC2700740/
https://ncbi.nlm.nih.gov/pubmed/20161262
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om800760x
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