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Highly Z- and Enantioselective Ring-Opening/Cross-Metathesis Reactions Catalyzed by Stereogenic-at-Mo Adamantylimido Complexes

The first highly Z- and enantioselective class of ring-opening/cross-metathesis (ROCM) reactions is presented. Transformations are promoted in the presence of <2 mol % of chiral stereogenic-at-Mo monoaryloxide complexes, which bear an adamantylimido ligand and are prepared and used in situ. React...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Ibrahem, Ismail, Yu, Miao, Schrock, Richard R., Hoveyda, Amir H.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2009
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2681245/
https://ncbi.nlm.nih.gov/pubmed/19249833
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja900097n
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