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Anion Catalyzed Addition of γ-Silylallenyl Esters to Aldehydes: A New Entry into [3.2.1] Bicyclic Natural Products
[Image: see text] A significant improvement in generality and reactivity of MBH-type reactions made possible by anion-catalysis and a 1,3-Brook rearrangement. In this new reaction, both aliphatic and aromatic aldehydes are rapidly added to silylallenes leading to γ-carbinol allenoates at cold temper...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2674362/ https://ncbi.nlm.nih.gov/pubmed/19271702 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja810136m |
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