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Selective One-Pot Synthesis of Allenyl and Alkynyl Esters from β-Ketoesters
A convenient method is described for the dehydration of β-ketoesters to generate conjugated and deconjugated alkynyl esters and conjugated allenyl esters. This sequential one-pot method involves the formation of a vinyl triflate monoanion intermediate that leads to the selective formation of alkynes...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2652892/ https://ncbi.nlm.nih.gov/pubmed/19063594 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801563x |
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