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Diversification Reactions of γ-Silyl Allenyl Esters: Selective Conversion to All-Carbon Quaternary Centers and γ-Allene Dicarbinols
The unique reactivity of γ-silyl allenyl esters is described. taking advantage of the silyl group as a fluoride acceptor, these allenoates readily underwent addition to a variety of electrophiles to selectively produce products with all-carbon quaternary centers or allenoate dicarbinols. these dicar...
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| Publicado no: | Chem Commun (Camb) |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5510162/ https://ncbi.nlm.nih.gov/pubmed/28435948 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc01708a |
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