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Directed Hydrozirconation of Propargylic Alcohols

[Image: see text] Hydrozirconation of terminal alkynes with Cp(2)ZrH(Cl) (Schwartz reagent) usually proceeds with high selectivity to yield the terminal vinyl zirconium. Under standard hydrozirconation conditions, terminal propargylic alcohols are no exception. However, we report that the sense of r...

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Bibliografski detalji
Glavni autori: Zhang, Donghui, Ready, Joseph M.
Format: Artigo
Jezik:Inglês
Izdano: 2007
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2669288/
https://ncbi.nlm.nih.gov/pubmed/17850152
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja075215o
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