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Directed Hydrozirconation of Homopropargylic Alcohols
Homopropargylic alcohols undergo directed hydrozirconation with Schwartz reagent (Cp(2)ZrHCl) to generate vinyl-metal species in which the metal fragment is proximal to the alkoxide. Electrophilic trapping yields tri-substituted olefins in good yields with good control of regio- and stereochemistry....
Na minha lista:
| Main Authors: | , |
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| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2008
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2516920/ https://ncbi.nlm.nih.gov/pubmed/19122870 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.03.052 |
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