Organometallic Enantiomeric Scaffolding. Sequential Semipinacol / 1,5-“Michael-like” Reactions as a Strategic Approach to Bridgehead-Quaternary Center Aza[3.3.1]Bicyclics: Application to the Total Synthesis of (-)-Adaline

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• Organometallic Enantiomeric Scaffolding. A Molybdenum-mediated Intramolecular Nucleophilic Ketalization-Demetalation Cascade. Total Synthesis of (+)-(1R,2S,5S,7R)-2-Hydroxy-exo-brevicomin
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