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Substituent Effects on the Rearrangements of Cyclohexyl to Cyclopentyl Radicals Involving Avermectin-related Radicals
The rearrangement of a substituted cyclohexyl radical to a cyclopentylmethyl radical on the skeleton of Avermectin B(1) has been investigated using density functional (UB3LYP/6-31G(d)) and G3MP2B3 computational methods. The rearrangement is preferred when highly radical stabilizing groups are presen...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2652414/ https://ncbi.nlm.nih.gov/pubmed/18842059 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo800923a |
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