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Substituent Effects in the Benzene Dimer are Due to Direct Interactions of the Substituents with the Unsubstituted Benzene

[Image: see text] The prevailing views of substituent effects in the sandwich configuration of the benzene dimer are flawed. For example, in the polar/π model of Cozzi and co-workers (J. Am. Chem. Soc. 1992, 114, 5729), electron-withdrawing substituents enhance binding in the benzene dimer by withdr...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Wheeler, Steven E., Houk, K. N.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2008
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC2655233/
https://ncbi.nlm.nih.gov/pubmed/18652453
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja802849j
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