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Probing Substituent Effects in Aryl-Aryl Interactions Using Stereoselective Diels-Alder Cycloadditions

Stereoselective Diels-Alder cycloadditions that probe substituent effects in aryl-aryl sandwich complexes were studied experimentally and theoretically. Computations on model systems demonstrate that the stereoselectivity in these reactions is mediated by differential π-stacking interactions in comp...

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Detalhes bibliográficos
Main Authors: Wheeler, Steven E., McNeil, Anne J., Müller, Peter, Swager, Timothy M., Houk, K. N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2838923/
https://ncbi.nlm.nih.gov/pubmed/20158182
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja903653j
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