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Ag-Catalyzed Diastereo- and Enantioselective Vinylogous Mannich Reactions of α-Ketoimine Esters. Development of a Method and Investigation of its Mechanism

An efficient diastereo- and enantioselective Ag-catalyzed method for additions of a commercially available siloxyfuran to α-ketoimine esters is disclosed. Catalytic transformations require an inexpensive metal salt (AgOAc) and an air stable chiral ligand that is prepared in three steps from commerci...

詳細記述

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書誌詳細
主要な著者: Wieland, Laura C., Vieira, Erika M., Snapper, Marc L., Hoveyda, Amir H.
フォーマット: Artigo
言語:Inglês
出版事項: 2009
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC2645437/
https://ncbi.nlm.nih.gov/pubmed/18980303
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8062315
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