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De Novo Asymmetric Synthesis of Milbemycin β(3) via an Iterative Asymmetric Hydration Approach
[Figure: see text] The enantioselective synthesis of the spiroketal/macrolide natural product milbemycin β(3) has been achieved in 22 steps and 2.8% overall yield from an achiral dienoate. The spiroketal ring system was installed by three sequential asymmetric hydrations followed by sprioketalizatio...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2615677/ https://ncbi.nlm.nih.gov/pubmed/16928055 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol061439k |
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