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Asymmetric Intramolecular Arylcyanation of Unactivated Olefins via C–CN Bond Activation
[Image: see text] The enantioselective, intramolecular arylcyanation of unactivated olefins via C–CN bond activation has been accomplished using a Ni(0) catalyst and BPh(3) co-catalyst. High enantioselectivities are achieved using TangPHOS as a chiral ligand. This method allows generation of two new...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2008
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2596758/ https://ncbi.nlm.nih.gov/pubmed/18761453 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja805094j |
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