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Intramolecular Acetyl Transfer to Olefins by Catalytic C–C Bond Activation of Unstrained Ketones
A rhodium-catalyzed intramolecular acetyl-group transfer has been achieved through a “cut and sew” process. The challenge arises from the existence of different competitive pathways. Preliminary success has been achieved with unstrained enones that contain a biaryl linker. The use of an electron-ric...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5798000/ https://ncbi.nlm.nih.gov/pubmed/29171904 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201711394 |
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