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Intramolecular Acetyl Transfer to Olefins by Catalytic C–C Bond Activation of Unstrained Ketones

A rhodium-catalyzed intramolecular acetyl-group transfer has been achieved through a “cut and sew” process. The challenge arises from the existence of different competitive pathways. Preliminary success has been achieved with unstrained enones that contain a biaryl linker. The use of an electron-ric...

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Bibliografiska uppgifter
I publikationen:Angew Chem Int Ed Engl
Huvudupphovsmän: Rong, Zi-Qiang, Lim, Hee Nam, Dong, Guangbin
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2017
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC5798000/
https://ncbi.nlm.nih.gov/pubmed/29171904
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201711394
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