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Catalytic, Enantioselective, Intramolecular Carbosulfenylation of Olefins
The first catalytic, enantioselective carbosulfenylation of alkenes with an aromatic nucleophile is described, using a BINAM-based selenophosphoramide catalyst. E-Alkyl- and aryl-substituted alkenes afforded tetrahydronaphthalenes with complete diastereospecificity, and generally high enantiomeric r...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3675264/ https://ncbi.nlm.nih.gov/pubmed/23597174 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja401867b |
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