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Intramolecular Aminocyanation of Alkenes via N–CN Bond Cleavage
A metal-free, Lewis acid-promoted intramolecular aminocyanation of alkenes was developed. B(C(6)F(5))(3) activates N-sulfonyl cyanamides, leading an formal cleavage of the N-CN bonds in conjunction with vicinal addition of sulfonamide and nitrile groups across an alkene. This method enables atom-eco...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4077192/ https://ncbi.nlm.nih.gov/pubmed/24719371 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201310983 |
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