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Enantioselective Intramolecular Hydroarylation of Alkenes via Directed C–H Bond Activation

[Image: see text] Highly enantioselective catalytic intramolecular ortho-alkylation of aromatic imines containing alkenyl groups tethered at the meta position relative to the imine directing group has been achieved using [RhCl(coe)(2)](2) and chiral phosphoramidite ligands. Cyclization of substrates...

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Detalhes bibliográficos
Main Authors: Harada, Hitoshi, Thalji, Reema K., Bergman, Robert G., Ellman, Jonathan A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2610454/
https://ncbi.nlm.nih.gov/pubmed/18681407
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo801098z
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