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Asymmetric Synthesis of (−)-Incarvillateine Employing an Intramolecular Alkylation via Rh-Catalyzed Olefinic C–H Bond Activation
[Image: see text] An asymmetric total synthesis of (–)-incarvillateine, a natural product having potent analgesic properties, has been achieved in 11 steps and 15.4% overall yield. The key step is a rhodium-catalyzed intramolecular alkylation of an olefinic C – H bond to set two stereocenters. Addit...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2008
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2713182/ https://ncbi.nlm.nih.gov/pubmed/18444613 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8012159 |
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