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Intramolecular Aminocyanation of Alkenes via N–CN Bond Cleavage

A metal-free, Lewis acid-promoted intramolecular aminocyanation of alkenes was developed. B(C(6)F(5))(3) activates N-sulfonyl cyanamides, leading an formal cleavage of the N-CN bonds in conjunction with vicinal addition of sulfonamide and nitrile groups across an alkene. This method enables atom-eco...

Deskribapen osoa

Gorde:
Xehetasun bibliografikoak
Egile Nagusiak: Pan, Zhongda, Pound, Sarah M., Rondla, Naveen R., Douglas, Christopher J.
Formatua: Artigo
Hizkuntza:Inglês
Argitaratua: 2014
Gaiak:
Sarrera elektronikoa:https://ncbi.nlm.nih.gov/pmc/articles/PMC4077192/
https://ncbi.nlm.nih.gov/pubmed/24719371
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201310983
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