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Mechanistic Studies of Ce(IV)-Mediated Oxidation of β-Dicarbonyls: Solvent-Dependent Behavior of Radical Cation Intermediates
The Ce(IV) initiated oxidation of synthetically relevant β-diketones and β-keto silyl enol ethers were explored in three solvents: acetonitrile, methylene chloride, and methanol. The studies presented herein show that the rate of reaction between Ce(IV) and the substrates is dependent upon the polar...
Gorde:
| Egile Nagusiak: | , , , , , |
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| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2007
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2593826/ https://ncbi.nlm.nih.gov/pubmed/17602587 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo0625406 |
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