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Solvent-dependent oxidative coupling of 1-aryl-1,3-dicarbonyls and styrene

This report describes the scope and mechanism of the solvent-dependent, chemoselective oxidative coupling of 1-aryl-1,3-dicarbonyls with styrene using Ce(IV) reagents. Dihydrofuran derivatives are obtained when reactions are performed in methanol whereas α-tetralones can be selectively synthesized i...

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Detalhes bibliográficos
Main Authors: Casey, Brian M., Eakin, Cynthia A., Jiao, Jingliang, Sadasivam, Dhandapani V., Flowers, Robert A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2898135/
https://ncbi.nlm.nih.gov/pubmed/20625455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2009.06.118
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