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Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds

The synthesis of 2-tetralones through the cyclization of δ-aryl-β-dicarbonyl substrates by using CAN is described. Appropriately functionalized aromatic substrates undergo intramolecular cyclizations generating 2-tetralone derivatives in moderate to good yields. DFT computational studies indicate th...

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Detalhes bibliográficos
Main Authors: Casey, Brian M, Sadasivam, Dhandapani V, Flowers II, Robert A
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3740710/
https://ncbi.nlm.nih.gov/pubmed/23946845
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.167
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