Spectroscopic and DFT Investigation of [M{HB(3,5-(i)Pr(2)pz)(3)}(SC(6)F(5))] (M = Mn, Fe, Co, Ni, Cu, and Zn) Model Complexes: Periodic Trends in Metal-thiolate Bonding

A series of metal-varied model complexes [ML(SC(6)F(5))] (where L = hydrotris(3,5-diisopropyl-1-pyrazolyl)borate and M = Mn, Fe, Co, Ni, Cu, and Zn) related to blue copper proteins has been studied by the combination of absorption, MCD, resonance Raman, and S K-edge X-ray absorption spectroscopies....

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Main Authors: Gorelsky, Serge I., Basumallick, Lipika, Vura-Weis, Josh, Sarangi, Ritimukta, Hodgson, Keith O., Hedman, Britt, Fujisawa, Kiyoshi, Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado: 2005
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2593087/
https://ncbi.nlm.nih.gov/pubmed/15998022
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic050371m
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