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Spectroscopic and Density Functional Theory Studies of the Blue–Copper Site in M121SeM and C112SeC Azurin: Cu–Se Versus Cu–S Bonding

S K-edge X-ray absorption, UV–vis absorption, magnetic circular dichroism (MCD), and resonance Raman spectroscopies are used to investigate the electronic structure differences among WT, M121SeM, and C112SeC Pseudomonas aeruginosa (P.a) azurin. A comparison of S K-edge XAS of WT and M121SeM azurin a...

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Detalhes bibliográficos
Main Authors: Sarangi, Ritimukta, Gorelsky, Serge I., Basumallick, Lipika, Hwang, Hee Jung, Pratt, Russell C., Stack, T. Daniel P., Lu, Yi, Hodgson, Keith O., Hedman, Britt, Solomon, Edward I.
Formato: Artigo
Idioma:Inglês
Publicado em: 2008
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2713798/
https://ncbi.nlm.nih.gov/pubmed/18314977
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja076495a
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