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Outer-Sphere Effects on Reduction Potentials of Copper Sites in Proteins: The Curious Case of High Potential Type 2 C112D/M121E Pseudomonas aeruginosa Azurin

Redox and spectroscopic (electronic absorption, multifrequency electron paramagnetic resonance (EPR), and X-ray absorption) properties together with X-ray crystal structures are reported for the type 2 Cu(II) C112D/M121E variant of Pseudomonas aeruginosa azurin. The results suggest that Cu(II) is co...

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Main Authors: Lancaster, Kyle M., Sproules, Stephen, Palmer, Joshua H., Richards, John H., Gray, Harry B.
Format: Artigo
Jezik:Inglês
Izdano: 2010
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3375907/
https://ncbi.nlm.nih.gov/pubmed/20879734
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105731x
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