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Asymmetric Eschenmoser–Claisen Rearrangement for Anti-β-Substituted γ,δ-Unsaturated Amino Acids
Optically active anti-β-substituted γ,δ-unsaturated amino acids are important synthetic building blocks in organic synthesis and for peptidomimetics. A novel asymmetric Eschenmoser–Claisen rearrangement with use of a C(2)-symmetric chiral auxiliary was developed to generate this type of amino acid....
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2587277/ https://ncbi.nlm.nih.gov/pubmed/17760455 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol701704h |
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