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Facile Concerted Proton-Electron Transfers in a Ruthenium Terpyridine-4′-Carboxylate Complex with a Long Distance Between the Redox and Basic Sites
We have designed and prepared ruthenium complexes with terpyridine-4′-carboxylate (tpyCOO) ligands, in which there are six bonds between the redox-active Ru and the basic carboxylate. The protonated Ru(II) complex, Ru(II)(dipic)(tpyCOOH) (Ru(II)COOH), is prepared in one-pot from [(p-cymene)RuCl(2)](...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2562563/ https://ncbi.nlm.nih.gov/pubmed/18479096 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja801672w |
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